Are there pesticides that kill bed bugs? Yup. There sure are. Pest control companies often use pesticides to exterminate these bugs as part of a heat treatment, and also by themselves. But chemicals have some drawbacks that pest professionals are aware of. These products can drive bed bugs into walls, like an improperly applied heat treatment, and they can be ineffectual if bed bugs are deep inside furniture. There are also safety considerations that need to be considered when applying any pesticide.
Although bedbugs are generally nocturnal, they're like humans—if they're hungry, they'll get up and get something to eat. "If you go away to visit a friend for a week and you come back and sit down on the couch, even though it's daytime the bedbugs will come looking for you," Schal says. Keeping a light on, then, unfortunately does not keep these tiny vampires away. 

Bedbugs can live in any area of the home and use tiny cracks in furniture as well as on textiles and upholstered furniture as hiding places. They tend to be most common in areas where people sleep and generally concentrate in beds, including mattresses or mattress covers, box springs, and bed frames. They do not infest the sleeping surfaces of beds as commonly as cracks and crevices associated with the bed frame and mattress. Other sites where bedbugs often reside include curtains, edges of carpet, corners inside dressers and other furniture, cracks in wallpaper (particularly near the bed), and inside the spaces of wicker furniture.

Bed bugs are active mainly at night. During the daytime, they prefer to hide close to where people sleep. Their flattened bodies enable them to fit into tiny crevices--especially those associated with mattresses, box springs, bed frames and headboards. Bed bugs do not have nests like ants or bees, but do tend to congregate in habitual hiding places. Characteristically, these areas are marked by dark spotting and staining, which is the dried excrement of the bugs. Also present will be hatched and un-hatched eggs, the tannish shed skins of maturing nymphs, and the bugs themselves. Another possible sign are rusty or reddish smears on bed sheets or mattresses from crushed engorged bed bugs. Although it’s often stated that bed bugs have a telltale “buggy” odor, the smell is seldom evident except in extreme infestations and should not be relied upon for detection.
Well, among others, you would want to purchase Bed Bug Bully. As stated in FIFRA 25 (b), it is a minimum-risk pesticide. That’s because it is made with organic-based products. More than that, pest-control companies already proved that they truly work withtheir continuous use of it. And with its new licensing agreement, you could also now enjoy its effectiveness, safety and affordability.
The creatures don't have wings and they can't fly or jump. But their narrow body shape and ability to live for months without food make them ready stowaways and squatters. Bedbugs can easily hide in the seams and folds of luggage, bags and clothes. They also take shelter behind wallpaper and inside bedding, box springs and furniture. The ones that feed on people can crawl more than 100 feet (30 meters) in a night, but typically creep to within 8 feet (2.4 m) of the spot its human hosts sleep, according to the CDC.
^ Kambu, Kabangu; Di Phanzu, N.; Coune, Claude; Wauters, Jean-Noël; Angenot, Luc (1982). "Contribution à l'étude des propriétés insecticides et chimiques d'Eucalyptus saligna du Zaïre (Contribution to the study of insecticide and chemical properties of Eucalyptus saligna from Zaire ( Congo))". Plantes Médicinales et Phytothérapie. 16 (1): 34–38. hdl:2268/14438.

Select and use insecticides safely. There are no magic sprays that kill bed bugs very well.  Most commercial insecticides will kill bed bugs if applied carefully and directly to the insects and their hiding places. An exception is “Bug bombs”, or aerosol foggers. Foggers are mostly ineffective in controlling bed bugs. Because bed bugs hide in crevices and voids where aerosols do not penetrate, they are able to avoid contact with these insecticides. Their use is not recommended. Some of the products you may find helpful include:

Spectre 2 SC has a low odor and is not dectectable by the bed bugs. Adjust the spray pattern to a mist by turning the nozzle. A low fine mist is best for most spraying, but you may need to use a stream to get into some cracks and crevices. If you can't get into the cracks and crevices use one of the aerosols described below with it's crack and crevice tips to reach into these areas.
Bedbugs do, however, have a unique bite pattern. Although some bites may appear alone, most bites occur in a row of three to five bites (termed "breakfast, lunch, and dinner") or in a cluster of red bumps (a rash called bedbug dermatitis). The bites often appear in a zig-zag formation, but may appear in a straight line if the bugs bite you in the morning.
Bedbugs may enter your home undetected through luggage, clothing, used beds and couches, and other items. Their flattened bodies make it possible for them to fit into tiny spaces, about the width of a credit card. Bedbugs do not have nests like ants or bees, but tend to live in groups in hiding places. Their initial hiding places are typically in mattresses, box springs, bed frames, and headboards where they have easy access to people to bite in the night. 

Bed bugs multiply quickly, and in just six months, a few can turn into a full-on infestation of 13,000 or more. Detection is critical to break the bed bug life cycle before they become a bigger problem. Orkin Bed Bug Detection Service gets to the root of the problem with targeted inspections of common bed bug hiding places in your home and ongoing monitoring to ensure the pests never return.
The life cycle stages of a bed bug are egg, nymph, and adult. The reason they are called bed bugs is that they readily infest mattresses, bed frames and box springs. Eggs are laid along the edges of or around buttons on the mattresses. Eggs can also be glued to rough surfaces. Bed bug females lay about 200 eggs, usually at the rate of three or four a day. Eggs are placed in cracks, crevices and other isolated and protected shelters. Females lay eggs after a blood meal. Eggs will hatch in one or two weeks into Nymphs. Newly hatched bugs (Nymphs) begin feeding immediately. At room temperature, and with an available food supply, the nymphal period will last 14 to 30 days. They shed their skin (Instar) five times before becoming adults. Bed bugs will mate soon after becoming mature, so the time from egg hatch to egg laying is 4 to 9 weeks, under favorable conditions. The average life span of the bed bug is 6-12 months and they feed every 10 days or so during this time. Bed bugs can survive many months without a blood meal and their reproduction is high.
One of the many uses of tea tree oil around the house is to use it as a DIY natural bed bug spray. Tea tree oil contains compounds that have an insecticidal effect against insects as well as their larvae and eggs. Although no direct studies have been published on the effect of tea tree oil on bed bugs, research has shown that it has a lethal effect on many bugs and insects.
Heat Treatment – this method kills bed bugs with heat. This could be implemented on clothes by putting them in a drier at a high temperature for 30 minutes. In a room, the use of heating devices could kill even the eggs and the nymphs of bed bugs at certain levels temperature at different durations of time. Ideally, to kill bed bugs in all stages, the temperature must be 115 degrees F or 46 degrees C.
×